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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491248Generated: October 31, 2026

3-Bromotoluene → 2-(3-Bromo-5-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

https://huagongshe.com/reaction/1491248

Reaction equation

Participants

RoleNameHCIDCharge
Reactant3-BromotolueneHCID 11560—
ReagentDodecahydrotriphenyleneHCID 95278—
Reagent4,4,5,5-Tetramethyl[1,3,2]dioxaborolaneHCID 2734768—
Reagent4,4'-Di-tert-butyl-2,2'-bipyridylHCID 4249187—
CatalystBis(1,5-cyclooctadiene)dimethoxydiiridiumHCID 76001521—
SolventTetrahydrofuranHCID 8028—
Product2-(3-Bromo-5-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolaneHCID 5342905640%

Reaction Conditions

Temperature25 °C

Provenance & Evidence

DOI10.1021/ja400295v
Source datasetBorylation dataset from Roche
ORD IDord-a66a1229ea16463496853e9241980737
Source noteBorylation dataset from Roche