HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491254Generated: November 3, 2026
3-Bromotoluene → 2-(3-Bromo-5-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
https://huagongshe.com/reaction/1491254
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 3-Bromotoluene | HCID 11560 | — |
| Reagent | Dodecahydrotriphenylene | HCID 95278 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Reagent | 4,4'-Di-tert-butyl-2,2'-bipyridyl | HCID 4249187 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | 2-(3-Bromo-5-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane | HCID 53429056 | 54% |
Provenance & Evidence
| DOI | 10.1021/ja400295v |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-422cb4ab13e34987a8bf1b48f50a8906 |
|---|
| Source note | Borylation dataset from Roche |
|---|
