HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491257Generated: November 1, 2026
3-Bromotoluene → 2-(3-Bromo-5-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
https://huagongshe.com/reaction/1491257
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 3-Bromotoluene | HCID 11560 | — |
| Reagent | 3,4,7,8-Tetramethyl-1,10-phenanthroline | HCID 74265 | — |
| Reagent | Dodecahydrotriphenylene | HCID 95278 | — |
| Reagent | 4,4,5,5-Tetramethyl[1,3,2]dioxaborolane | HCID 2734768 | — |
| Catalyst | Chloro-1,5-cyclooctadiene-iridium(I) dimer | HCID 82923 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | 2-(3-Bromo-5-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane | HCID 53429056 | 0% |
Provenance & Evidence
| DOI | 10.1021/ja400295v |
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| Source dataset | Borylation dataset from Roche |
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| ORD ID | ord-d393ef93905544968cc0b7954da9bacc |
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| Source note | Borylation dataset from Roche |
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