HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491301Generated: October 30, 2026
1,2,3-Trimethoxybenzene → 4,4,5,5-Tetramethyl-2-(3,4,5-trimethoxyphenyl)-1,3,2-dioxaborolane
https://huagongshe.com/reaction/1491301
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 1,2,3-Trimethoxybenzene | HCID 12462 | — |
| Reagent | 3,4,7,8-Tetramethyl-1,10-phenanthroline | HCID 74265 | — |
| Reagent | Dodecahydrotriphenylene | HCID 95278 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | 4,4,5,5-Tetramethyl-2-(3,4,5-trimethoxyphenyl)-1,3,2-dioxaborolane | HCID 21923946 | 8% |
Provenance & Evidence
| DOI | 10.1021/ja400295v |
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| Source dataset | Borylation dataset from Roche |
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| ORD ID | ord-6e15d3a4581f4895bf237d3005f85908 |
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| Source note | Borylation dataset from Roche |
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