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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491306Generated: October 31, 2026

1,2,3-Trimethoxybenzene → 4,4,5,5-Tetramethyl-2-(3,4,5-trimethoxyphenyl)-1,3,2-dioxaborolane

https://huagongshe.com/reaction/1491306

Reaction equation

Participants

RoleNameHCIDCharge
Reactant1,2,3-TrimethoxybenzeneHCID 12462—
ReagentDodecahydrotriphenyleneHCID 95278—
Reagent4,4,5,5-Tetramethyl[1,3,2]dioxaborolaneHCID 2734768—
Reagent4,4'-Di-tert-butyl-2,2'-bipyridylHCID 4249187—
CatalystBis(1,5-cyclooctadiene)dimethoxydiiridiumHCID 76001521—
SolventTetrahydrofuranHCID 8028—
Product4,4,5,5-Tetramethyl-2-(3,4,5-trimethoxyphenyl)-1,3,2-dioxaborolaneHCID 2192394641%

Reaction Conditions

Temperature80 °C

Provenance & Evidence

DOI10.1021/ja400295v
Source datasetBorylation dataset from Roche
ORD IDord-e47f68071def4e93a0d08ae1d0c94242
Source noteBorylation dataset from Roche