Back
HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491340Generated: October 31, 2026

3-Bromotoluene → 2-(3-Bromo-5-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

https://huagongshe.com/reaction/1491340

Reaction equation

Participants

RoleNameHCIDCharge
Reactant3-BromotolueneHCID 11560—
ReagentDodecahydrotriphenyleneHCID 95278—
Reagent4,4,5,5-Tetramethyl[1,3,2]dioxaborolaneHCID 2734768—
Reagent4,4'-Di-tert-butyl-2,2'-bipyridylHCID 4249187—
CatalystBis(1,5-cyclooctadiene)dimethoxydiiridiumHCID 76001521—
Solvent1,4-DioxaneHCID 31275—
Product2-(3-Bromo-5-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolaneHCID 5342905617%

Reaction Conditions

Temperature25 °C

Provenance & Evidence

DOI10.1021/ja400295v
Source datasetBorylation dataset from Roche
ORD IDord-f4a83ffd165640f3b822affad1832307
Source noteBorylation dataset from Roche