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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491342Generated: November 1, 2026

3-Bromotoluene → 2-(3-Bromo-5-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

https://huagongshe.com/reaction/1491342

Reaction equation

Participants

RoleNameHCIDCharge
Reactant3-BromotolueneHCID 11560—
Reagent3,4,7,8-Tetramethyl-1,10-phenanthrolineHCID 74265—
ReagentDodecahydrotriphenyleneHCID 95278—
Reagent4,4,5,5-Tetramethyl[1,3,2]dioxaborolaneHCID 2734768—
CatalystBis(1,5-cyclooctadiene)dimethoxydiiridiumHCID 76001521—
Solvent1,4-DioxaneHCID 31275—
Product2-(3-Bromo-5-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolaneHCID 5342905614%

Reaction Conditions

Temperature25 °C

Provenance & Evidence

DOI10.1021/ja400295v
Source datasetBorylation dataset from Roche
ORD IDord-3b489714646741cd9608f91236e8f566
Source noteBorylation dataset from Roche