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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491344Generated: October 30, 2026

3-Bromotoluene → 2-(3-Bromo-5-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

https://huagongshe.com/reaction/1491344

Reaction equation

Participants

RoleNameHCIDCharge
Reactant3-BromotolueneHCID 11560—
ReagentDodecahydrotriphenyleneHCID 95278—
Reagent4,4,5,5-Tetramethyl[1,3,2]dioxaborolaneHCID 2734768—
Reagent4,4'-Di-tert-butyl-2,2'-bipyridylHCID 4249187—
CatalystBis(1,5-cyclooctadiene)dimethoxydiiridiumHCID 76001521—
SolventDiisopropylethylamineHCID 81531—
Product2-(3-Bromo-5-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolaneHCID 5342905629%

Reaction Conditions

Temperature25 °C

Provenance & Evidence

DOI10.1021/ja400295v
Source datasetBorylation dataset from Roche
ORD IDord-9e2d0b627c21495b9ffaa9f3d8b1b9a6
Source noteBorylation dataset from Roche