HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491346Generated: October 31, 2026
3-Bromotoluene → 2-(3-Bromo-5-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
https://huagongshe.com/reaction/1491346
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 3-Bromotoluene | HCID 11560 | — |
| Reagent | 3,4,7,8-Tetramethyl-1,10-phenanthroline | HCID 74265 | — |
| Reagent | Dodecahydrotriphenylene | HCID 95278 | — |
| Reagent | 4,4,5,5-Tetramethyl[1,3,2]dioxaborolane | HCID 2734768 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | Diisopropylethylamine | HCID 81531 | — |
| Product | 2-(3-Bromo-5-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane | HCID 53429056 | 43% |
Provenance & Evidence
| DOI | 10.1021/ja400295v |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-0f454accf2dc47f989fdccfcad05fe01 |
|---|
| Source note | Borylation dataset from Roche |
|---|
