HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491348Generated: October 31, 2026
3-Bromotoluene → 2-(3-Bromo-5-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
https://huagongshe.com/reaction/1491348
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 3-Bromotoluene | HCID 11560 | — |
| Reagent | Dodecahydrotriphenylene | HCID 95278 | — |
| Reagent | 4,4,5,5-Tetramethyl[1,3,2]dioxaborolane | HCID 2734768 | — |
| Reagent | 4,4'-Di-tert-butyl-2,2'-bipyridyl | HCID 4249187 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | Triethylamine | HCID 8471 | — |
| Product | 2-(3-Bromo-5-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane | HCID 53429056 | 27% |
Provenance & Evidence
| DOI | 10.1021/ja400295v |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-14923c5f06a04294a9e2e9ab1ea80b5d |
|---|
| Source note | Borylation dataset from Roche |
|---|
