3-Bromotoluene → 2-(3-Bromo-5-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

HRID 1491361Notes

Reaction equation

HRID 1491361 reaction equation
Cc1cccc(Br)c1>C1CCc2c(c3c(c4c2CCCC4)CCCC3)C1.CC(=O)OC(C)C.CC1(C)OBOC1(C)C>Cc1cc(Br)cc(B2OC(C)(C)C(C)(C)O2)c1

Participants

5

Reactant 1

HCID 115603-Bromotoluene

Product 1

HCID 534290562-(3-Bromo-5-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolaneYield 41%

Reagents, catalysts & solvents 3

HCID 95278DodecahydrotriphenyleneReagentHCID 27347684,4,5,5-Tetramethyl[1,3,2]dioxaborolaneReagentHCID 7915Isopropyl AcetateSolvent

Conditions

Temperature
25 °C

Sources & evidence

ORD record
ord-50c5c91747d4441285a22a9beac7594b
Source dataset
Borylation dataset from Roche

Reaction notes

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