3-Bromotoluene → 2-(3-Bromo-5-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

HRID 1491373Notes

Reaction equation

HRID 1491373 reaction equation

Cc1cccc(Br)c1>C1CCc2c(c3c(c4c2CCCC4)CCCC3)C1.CC1(C)OBOC1(C)C.ClCCl>Cc1cc(Br)cc(B2OC(C)(C)C(C)(C)O2)c1

Participants

5

Reactant 1

HCID 115603-Bromotoluene

Product 1

HCID 534290562-(3-Bromo-5-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolaneYield 13%

Reagents, catalysts & solvents 3

HCID 95278DodecahydrotriphenyleneReagent

HCID 27347684,4,5,5-Tetramethyl[1,3,2]dioxaborolaneReagent

HCID 6344DichloromethaneSolvent

Conditions

Temperature: 25 °C

Sources & evidence

ORD record: ord-aa7b012fa31d41349b5323d1f9a59a48
Source dataset: Borylation dataset from Roche
DOI: 10.1021/ja400295v

Reaction notes

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