HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491465Generated: October 31, 2026
5-methyl-2-furonitrile → 5-Methyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)furan-2-carbonitrile
https://huagongshe.com/reaction/1491465
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 5-methyl-2-furonitrile | HCID 642108 | — |
| Reagent | 4,4,5,5-Tetramethyl[1,3,2]dioxaborolane | HCID 2734768 | — |
| Reagent | 4,4'-Di-tert-butyl-2,2'-bipyridyl | HCID 4249187 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | 5-Methyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)furan-2-carbonitrile | HCID 53435880 | 87% |
| Product | 5-Methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2-furancarbonitrile | HCID 57633882 | 10% |
Provenance & Evidence
| DOI | 10.1021/ja0428309 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-f9903988db4b4e0a875a9cdb79762a6c |
|---|
| Source note | Borylation dataset from Roche |
|---|