HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1491504Generated: October 30, 2026
1,1-Dimethyl-2-[(naphthalen-1-yl)methylidene]hydrazine → HCID 178484931, compound
https://huagongshe.com/reaction/1491504
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 1,1-Dimethyl-2-[(naphthalen-1-yl)methylidene]hydrazine | HCID 300508 | — |
| Reagent | Bis(pinacolato)diborane | HCID 2733548 | — |
| Reagent | 4,4,5,5-Tetramethyl[1,3,2]dioxaborolane | HCID 2734768 | — |
| Reagent | N,N-Dibenzyl-N'-(pyridin-2-ylmethylene)hydrazine | HCID 67601456 | — |
| Catalyst | Bis(1,5-cyclooctadiene)dimethoxydiiridium | HCID 76001521 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 178484931 | HCID 178484931 | 95% |
Reaction Steps
Following the general procedure, column chromatography in neutral alumina (EtOAc/n-hexane 1:8) afforded 11i (155 mg, 95 %) as a yellow oil.
Provenance & Evidence
| DOI | 10.1002/anie.201104544 |
|---|
| Source dataset | Borylation dataset from Roche |
|---|
| ORD ID | ord-04ef4005b699487e9a1d97d3cb0cd4bf |
|---|
| Source note | Borylation dataset from Roche |
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