HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,3-Dimethyl-2-imidazolidinone → 4-[2-(1,3-Dimethyl-2-imidazolidinylideneamino)phenyl]morpholine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,3-Dimethyl-2-imidazolidinone | HCID 6661 | — |
| Reactant | 2-Morpholinoaniline | HCID 735756 | — |
| Solvent | Benzene | HCID 241 | — |
| Solvent | Phosphorus oxychloride | HCID 24813 | — |
| Product | 4-[2-(1,3-Dimethyl-2-imidazolidinylideneamino)phenyl]morpholine | HCID 53789894 | — |
Reaction Steps
A mixture of 1,3-dimethyl-2-imidazolidinone (7 g) in benzene (45 ml), phosphorus oxychloride (6 ml) and 4-(2-aminophenyl)morpholine (8.5 g) in benzene (30 ml) was heated for 30 hours at 65°-70° C. The product was recrystallised from hexane to give 4-[2-(1,3-dimethyl-2-imidazolidinylideneamino)phenyl]morpholine (m.p. 133°-134° C.).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05373008 |
| Source dataset | uspto-grants-1994_12 |
| ORD ID | ord-a5925cd9cc6644fc9c71ff3a7afe706b |
| Source note | uspto-grants-1994_12 |