Potassium Hydroxide → HCID 18952191, compound

HRID 1492289Notes

Reaction equation

HRID 1492289 reaction equation
[CH3:1][C:2]1[C:3]([N:12]2[CH2:17][CH2:16][O:15][CH2:14][CH2:13]2)=[C:4]([NH:8][C:9]([NH2:11])=S)[CH:5]=[CH:6][CH:7]=1.O.O.O.C([O-])(=O)C.[Pb+2].C([O-])(=O)C.[OH-].[K+]>O>[CH3:1][C:2]1[C:3]([N:12]2[CH2:17][CH2:16][O:15][CH2:14][CH2:13]2)=[C:4]([NH:8][C:9]#[N:11])[CH:5]=[CH:6][CH:7]=1

Participants

5

Reactant 3

HCID 14797Potassium HydroxideHCID 22456Lead diacetate trihydrateHCID 15746479HCID 15746479, compound

Product 1

HCID 18952191HCID 18952191, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent3×

Procedure

A mixture of 1-(3-methyl-2-morpholinophenyl)thiourea (6 g) suspended in water (40 ml), lead acetate trihydrate (9 g) in water (40 ml), potassium hydroxide (13.5 g) in water (35 ml) was heated at 90°-95° C. for 1 hour to give N-(3-methyl-2-morpholinophenyl)cyanamide (m.p. 137°-138° C.) which was recrystallised from ethyl acetate.

Sources & evidence

ORD record
ord-f85db45869b6452f9336d6aa7769508f
Source dataset
uspto-grants-1994_12
Patent number
US05373008

Reaction notes

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