化工社化工社 化学情報印刷レポート · 研究参考用
3-(Trifluoromethyl)phenol → 2,6-Di-(3-trifluoromethyl phenoxy)-4-methylthiopyridine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 3-(Trifluoromethyl)phenol | HCID 7376 | — |
| 反応物 | Sodium hydride | HCID 24758 | — |
| 反応物 | 2,6-Dichloro-4-(methylthio)pyridine | HCID 18950231 | — |
| 生成物 | 2,6-Di-(3-trifluoromethyl phenoxy)-4-methylthiopyridine | HCID 21471060 | 85.3% |
反応手順
A mixture of 2,6-dichloro-4-methylthiopyridine (0.97 g; 0.005 mol), 3-hydroxybenzotrifluoride (1.3 ml; 10.4 mmol) and sodium hydride (0.2 g) was reacted and worked up according to the procedure of Example 1 above to give 2,6-di-(3-trifluoromethyl phenoxy)-4-methylthiopyridine (1.9 g; 85%)
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05374604 |
| 出典データセット | uspto-grants-1994_12 |
| ORD ID | ord-aa934b7d69004c628c57501ce6524b0d |
| 出典メモ | uspto-grants-1994_12 |