Sodium Hydroxide → HCID 18951567, compound

HRID 1492848Notes

Reaction equation

[OH-].[Na+].C[O:4][C:5](=[O:46])[C:6]1[CH:11]=[C:10]([O:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH3:26])[CH:9]=[C:8]([O:27][CH2:28][CH2:29][CH2:30][O:31][C:32]2[CH:37]=[CH:36][C:35]([O:38][CH2:39][C:40]3[CH:45]=[CH:44][CH:43]=[CH:42][CH:41]=3)=[CH:34][CH:33]=2)[CH:7]=1>>[C:40]1([CH2:39][O:38][C:35]2[CH:34]=[CH:33][C:32]([O:31][CH2:30][CH2:29][CH2:28][O:27][C:8]3[CH:7]=[C:6]([CH:11]=[C:10]([O:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH3:26])[CH:9]=3)[C:5]([OH:46])=[O:4])=[CH:37][CH:36]=2)[CH:41]=[CH:42][CH:43]=[CH:44][CH:45]=1

Participants

Reactant 2

HCID 14798Sodium Hydroxide

HCID 53728312HCID 53728312, compound

Product 1

HCID 18951567HCID 18951567, compoundYield 96%

Procedure

Sodium hydroxide hydrolysis of 3-[3-[4-(phenylmethoxy) phenoxy]propoxy]-5-(tetradecyloxy)benzoic acid methyl ester gave 3-[3-[4-(phenylmethoxy)phenoxy]propoxy]-5-(tetradecyloxy)benzoic acid (96% yield, mp 77°-79°).

Sources & evidence

ORD record: ord-43d489d61be74789a756fbf6310cc49c
Source dataset: uspto-grants-1994_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05374772

Reaction notes

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