HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Bromooctadecane → HCID 54090491, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Bromooctadecane | HCID 8218 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | Methyl 2,4-Dihydroxybenzoate | HCID 16523 | — |
| Solvent | Acetone | HCID 180 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | HCID 54090491 | HCID 54090491 | — |
Reaction Steps
A mixture of 1 g (5.95 mmol) of 2,4-dihydroxybenzoic acid methyl ester, 1.98 g (5.95 mmol) of 1-bromooctadecane and 0.825 g (5.95 mmol) of potassium carbonate was stirred at reflux for 40 hours in 20 ml of acetone and 2 ml of DMF. The usual workup followed by purification by HPLC using 1% ethyl acetate-hexane gave 2-hydroxy -4-(octadecyloxy)benzoic acid methyl ester, mp 61°-64°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05374772 |
| Source dataset | uspto-grants-1994_12 |
| ORD ID | ord-b48da143d76d441d9073cbfa0784014b |
| Source note | uspto-grants-1994_12 |