HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethanol → HCID 178476788, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | Chlorotrimethylsilane | HCID 6397 | — |
| Reactant | Ethyl diethoxymethyl(cyclohexylmethyl)phosphinate | HCID 19090914 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 178476788 | HCID 178476788 | — |
Reaction Steps
107 g of trimethylchlorosilane are added to a solution of 151 g of diethoxymethyl(cyclohexylmethyl)-phosphinic acid ethyl ester in 430 ml of dichloromethane that contains 10% by volume ethanol and the mixture is left to stand for 3 days at room temperature, then concentrated to dryness by evaporation and distilled under reduced pressure, yielding cyclohexylmethylphosphinic acid ethyl ester having a boiling point of 50° (3×10-4 bar).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05376684 |
| Source dataset | uspto-grants-1994_12 |
| ORD ID | ord-745580bba2754a078f86e3d127040c2f |
| Source note | uspto-grants-1994_12 |