HRID1493410

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CC(C)(C)c1cc(C(C)(C)C)c2op(Cl)oc3c(C(C)(C)C)cc(C(C)(C)C)cc3c2c1

HCID10983610

未命名化合物

HCID10997770

1-methoxy-2,2,6,6-tetramethyl-piperidin-4-ol

C10H21NO2

PRODUCTS

生成物

结构：CON1C(C)(C)CC(Op2oc3c(C(C)(C)C)cc(C(C)(C)C)cc3c3cc(C(C)(C)C)cc(C(C)(C)C)c3o2)CC1(C)C

HCID54110228

未命名化合物

PROCEDURE

实验过程

The title compound is prepared from 4-hydroxy-1-methoxy-2, 2,6,6-tetramethylpiperidine and 2,4,8,10-tetra-tert-butyl-6-chlorodibenzo [d,f][1,3,2]dioxaphosphepin according to the procedure of Example 1C.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-28206fa53ca743db8ccbdb4af4238b48
来源数据集: uspto-grants-1991_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05021481
来源说明: uspto-grants-1991_06

反应 SMILES

[OH:1][CH:2]1[CH2:7][C:6]([CH3:9])([CH3:8])[N:5]([O:10][CH3:11])[C:4]([CH3:13])([CH3:12])[CH2:3]1.[C:14]([C:18]1[CH:41]=[C:40]([C:42]([CH3:45])([CH3:44])[CH3:43])[C:21]2[O:22][P:23](Cl)[O:24][C:25]3[C:30]([C:31]([CH3:34])([CH3:33])[CH3:32])=[CH:29][C:28]([C:35]([CH3:38])([CH3:37])[CH3:36])=[CH:27][C:26]=3[C:20]=2[CH:19]=1)([CH3:17])([CH3:16])[CH3:15]>>[C:35]([C:28]1[CH:29]=[C:30]([C:31]([CH3:34])([CH3:33])[CH3:32])[C:25]2[O:24][P:23]([O:1][CH:2]3[CH2:7][C:6]([CH3:8])([CH3:9])[N:5]([O:10][CH3:11])[C:4]([CH3:13])([CH3:12])[CH2:3]3)[O:22][C:21]3[C:40]([C:42]([CH3:44])([CH3:43])[CH3:45])=[CH:41][C:18]([C:14]([CH3:17])([CH3:16])[CH3:15])=[CH:19][C:20]=3[C:26]=2[CH:27]=1)([CH3:38])([CH3:37])[CH3:36]