Ethane → Zinc bis(trifluoroacetate)

Participants

Reaction Conditions

Reaction Steps

A solution of diethyl zinc (27.5 mL, 1.1M in toluene) was slowly added to a solution of trifluoroacetic acid (2.77 mL) in dry toluene at -40° C. The reaction temp and the extent of ethane evolution was monitored. After stirring at -40° C. for 30 min, the solution was warmed to room temperature and trifluoroacetic acid (2.77 mL) was slowly added. The mixture was stirred overnight at room temperature, followed by refluxing for 2 h. A foaming suspension with a slight violet tint was formed. All volatiles were evaporated and the solid was dried at 80° C. under high vacuum. Yield: 7.65 g; 13C-NMR (75 MHz, Methanol-d4): 117.93 ppm (q, I=290.3 Hz, CF3), 163.7 ppm (q, I=36.6 Hz, CO).

Provenance & Evidence