Triacetoxyperiodinane → HCID 84717520, compound

Participants

Reaction Steps

In dichloromethane (10 ml), (1-ethyl-1H-indazol-5-yl)methanol (0.3 g, 1.70 mmol) prepared in Example 4-3 was dissolved, and 1,1,1-triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one (1.0 g, 2.38 mmol) was added thereto. The mixture was stirred for 2 hours. The mixture was subjected to extraction with chloroform, and the extract was dried over anhydrous magnesium sulfate and then concentrated. The concentrate was purified by silica gel column chromatography (dichloromethane:methanol=20:1) to give the title compound.

Provenance & Evidence