HuagongsheHuagongshe Chemistry Print Report · For research reference only
Isopropanol → HCID 11241820, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Isopropanol | HCID 3776 | — |
| Reactant | Hexane | HCID 8058 | — |
| Reactant | 3-Methylbutanal | HCID 11552 | — |
| Reactant | beta-nitrostyrene, (E)- | HCID 5284459 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | HCID 11241820 | HCID 11241820 | — |
Reaction Steps
The title compound was prepared from isovaleraldehyde and (E)-(2-nitrovinyl)benzene according to the general procedure. The enantiomeric excess was determined by HPLC with an AD-H column at 210 nm (2-propanol:hexane=1:99), 1.0 mL/min; major enantiomer tmajor=21.8 min, minor enantiomer tminor=17.9 min, the diastereomeric ratio was determined by 1H NMR. [α]D20=−6.5 (c=2.3, CHCl3).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09206090B2 |
| Source dataset | uspto-grants-2015_12 |
| ORD ID | ord-2d7dc970fbf14b2aba7ae97dfbc6e246 |
| Source note | uspto-grants-2015_12 |