Nitrobenzene → HCID 131734301, compound

Participants

Reaction Steps

The 3,6-bis(4-triphenylsilylphenyl)carbazole (1.30 g), 4-(8-hydroxyoctyloxy)iodobenzene (0.65 g), potassium carbonate (0.54 g), copper powder (0.4 g) and nitrobenzene (5 mL) were stirred under nitrogen flow at 195° C. for 16 hours. The resultant mixture was filtrated through CELITE and the solvent was evaporated. The residue was treated through silica gel column chromatography (eluent: 10% ethyl acetate/toluene solution), to thereby obtain 1.50 g (89.8%) of 3,6-bis(4-triphenylsilylphenyl)-N-[4-(8-hydroxyoctyloxyphenyl]carbazole as colorless needle crystals.

Provenance & Evidence