HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl Acetate → HCID 68001502, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl Acetate | HCID 8857 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | Butanoic acid, 2-bromo-, ethyl ester | HCID 79039 | — |
| Reactant | 2-Bromobenzenethiol | HCID 80598 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | HCID 68001502 | HCID 68001502 | — |
Reaction Steps
A mixture of 2-bromothiophenol (0.99 g, 5.0 mmol), ethyl 2-bromobutyrate (1.17 g, 6.0 mmol) and K2CO3 (0.966 g, 7.0 mmol) in DMF (2 mL) was stirred at room temperature for 2 hours. Ethyl acetate was added and the organic phase washed with brine, dried (MgSO4), concentrated and purified by chromatography to yield ethyl 2-(2-bromophenylthio)-2-methylpropanoate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09212135B2 |
| Source dataset | uspto-grants-2015_12 |
| ORD ID | ord-8df08a0d37a641d39fe68ab21f18c79d |
| Source note | uspto-grants-2015_12 |