HuagongsheHuagongshe Chemistry Print Report · For research reference only
Azobisisobutyronitrile → Ethylene carbonate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Azobisisobutyronitrile | HCID 6547 | — |
| Reactant | Benzoyl Peroxide | HCID 7187 | — |
| Reactant | Lauroyl peroxide | HCID 7773 | — |
| Reactant | HCID 22253865 | HCID 22253865 | — |
| Solvent | 1,2-Dichloroethane | HCID 11 | — |
| Solvent | Acetone | HCID 180 | — |
| Solvent | Benzene | HCID 241 | — |
| Solvent | Ethanol | HCID 702 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Solvent | Methyl Ethyl Ketone | HCID 6569 | — |
| Solvent | Propylene Carbonate | HCID 7924 | — |
| Solvent | 1,2-Dimethoxyethane | HCID 8071 | — |
| Product | Ethylene carbonate | HCID 7303 | — |
| Product | Diethyl Carbonate | HCID 7766 | — |
| Product | Dimethyl Carbonate | HCID 12021 | — |
Reaction Steps
In a phosphinylation polymerization, each X and Y are R9HP— and G is a hydrocarbyl, which includes a silicone. Copolymerization occurs in the presence of a radical initiator such as AIBN, V-40, benzoyl peroxide, lauroyl peroxide (Luperox™), UV light (λ≦400 nm), 2,2-dimethoxyphenyl acetophenone (Irgacure® 651), and the like, in a solvent such as benzene, acetone, ethanol, 1,2-dichloroethane, propylene carbonate, dimethyl carbonate, diethyl carbonate, ethylene carbonate, butanone, ethylene glycol dimethyl ether, or DMF at a temperature of 25 to 140° C. to produce the polymer.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09221844B2 |
| Source dataset | uspto-grants-2015_12 |
| ORD ID | ord-78c52039b4ce41ef9713739f9492c1d8 |
| Source note | uspto-grants-2015_12 |