Methanol → (7,9-Dihydroxy-5-(hydroxymethyl)-1,1a,2,8,9,9a-hexahydro-3,9-epoxyazireno(2,3-c)(1)benzazocin-8-yl)methyl hydrogen carbonimidate

HRID 151012Notes

Reaction equation

HRID 151012 reaction equation
[BH4-:24].[C:1]([NH2:2])([O:3][CH2:4][CH:5]1[c:6]2[c:7]([OH:22])[cH:8][c:9]([CH:20]=[O:21])[cH:10][c:11]2[N:12]2[CH2:13][CH:14]3[NH:15][CH:16]3[C:17]1([OH:19])[O:18]2)=[O:23].[CH3:26][OH:27].[Na+:25]>>[C:1]([NH2:2])([O:3][CH2:4][CH:5]1[c:6]2[c:7]([OH:22])[cH:8][c:9]([CH2:20][OH:21])[cH:10][c:11]2[N:12]2[CH2:13][CH:14]3[NH:15][CH:16]3[C:17]1([OH:19])[O:18]2)=[O:23]

Participants

5

Reactant 4

HCID 887MethanolHCID 923Sodium ionHCID 28123BorohydrideHCID 10448726(4-Formyl-6,9-dihydroxy-14-oxa-1,11-diazatetracyclo[7.4.1.02,7.010,12]tetradeca-2(7),3,5-trien-8-yl)methyl carbamate

Product 1

HCID 124136(7,9-Dihydroxy-5-(hydroxymethyl)-1,1a,2,8,9,9a-hexahydro-3,9-epoxyazireno(2,3-c)(1)benzazocin-8-yl)methyl hydrogen carbonimidate

Sources & evidence

ORD record
ord-4b2e02b84df94bb99f54f62584a2bd79
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

Loading…