1-Tetradecanol → Myristyl myristate

HRID 1511511Notes

Reaction equation

HRID 1511511 reaction equation
[CH2:1]([OH:15])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].[C:16](O)(=[O:30])[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29]>O>[C:1]([O:30][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])(=[O:15])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14]

Participants

4

Reactant 2

HCID 82091-TetradecanolHCID 11005Myristic Acid

Product 1

HCID 18605Myristyl myristate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

329 g of myristyl alcohol and 351 g of myristic acid were heated to 60° C. in a 1 L initial charge vessel and mixed by means of a magnetic stirrer. 2.72 g of Novozym 435 were added and the water of reaction formed was removed by applying a vacuum of 5 mbar, and the water was distilled off. The course of the reaction was monitored for ˜24 h by means of acid number titration (cf. Table 1).

Workup

  1. additioninitial charge vessel
  2. additionmixed by means of a magnetic stirrer
  3. addition2.72 g of Novozym 435 were added
  4. customformed
  5. customwas removed
  6. distillationthe water was distilled off

Sources & evidence

ORD record
ord-9847fff68ab84598a466187e101aa5e3
Source dataset
uspto-grants-2012_07
Patent number
US08216813B2

Reaction notes

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