化工社化工社 化学情報印刷レポート · 研究参考用
(alphaS)-alpha-Aminocyclohexaneacetic acid → (2S)-Cyclohexyl({[(2,2-dimethylhex-5-en-1-yl)oxy]carbonyl}amino)acetic acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | (alphaS)-alpha-Aminocyclohexaneacetic acid | HCID 736848 | — |
| 反応物 | 2,2-Dimethylhex-5-en-1-ol | HCID 10240821 | — |
| 反応物 | 3-Methyl-N-{[(pent-4-en-1-yl)oxy]carbonyl}-L-valine | HCID 45379928 | — |
| 生成物 | (2S)-Cyclohexyl({[(2,2-dimethylhex-5-en-1-yl)oxy]carbonyl}amino)acetic acid | HCID 45379612 | — |
反応手順
(2S)-Cyclohexyl({[(2,2-dimethylhex-5-en-1-yl)oxy]carbonyl}amino)acetic acid was prepared according to the procedure for 3-methyl-N-[(pent-4-enyloxy)carbonyl]-L-valine using (2S)-amino(cyclohexyl)acetic acid and 2,2-dimethylhex-5-en-1-ol. LRMS (ESI) m/z 312.3 [(M+H)+; calcd for C17H30NO4: 312.2].
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08216999B2 |
| 出典データセット | uspto-grants-2012_07 |
| ORD ID | ord-3beae7aac3094a5e874349abe5fceef8 |
| 出典メモ | uspto-grants-2012_07 |