2-Bromo-6-phenylpyridine → HCID 59722065, compound

Participants

Reaction Steps

2-Bromo-6-phenylpyridine 2.5 g (11 mmol), 9,10-diphenylanthracene-2-boronic acid 4.9 g (13 mmol) and tetrakis(triphenylphosphine)palladium 0.25 g (0.22 mmol) were dissolved in 60 mL of 12-dimethoxyethane. A 2.0M sodium carbonate aqueous solution 30 mL was added thereto, and the solution was refluxed for 8 hours under argon atmosphere by heating. After finishing the reaction, the solution was filtered, and a solid matter obtained was washed with water, methanol and toluene to obtain 4.5 g (yield: 84%) of a greenish white solid matter. Mass spectral analysis of the above solid matter resulted in confirming that the measured value m/e was 483 versus a molecular weight of 483.20 and that it was the aimed compound 1

Provenance & Evidence