関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 2-Hydroxyethyl acrylate | HCID 13165 | — |
| 反応物 | 2,6-Di-tert-butyl-4-methylphenol | HCID 31404 | — |
| 反応物 | N,N',N''-Tris(3-dimethylaminopropyl)hexahydro-S-triazine | HCID 85160 | — |
| 反応物 | Isocyanate | HCID 105034 | — |
| 反応物 | 3-(Methylthio)phenyl isocyanate | HCID 141418 | — |
| 生成物 | 2-(((3-(Methylsulfanyl)phenyl)carbamoyl)oxy)ethyl prop-2-enoate | HCID 59273262 | — |
反応手順
0.02 g of 2,6-di-tert-butyl-4-methylphenol, 0.01 g of Desmorapid Z, 11.7 g of 3-(methylthio)phenyl isocyanate were initially introduced into a 100 ml round-bottomed flask and heated to 60° C. Thereafter, 8.2 g of 2-hydroxyethyl acrylate were added dropwise and the mixture was kept farther at 60° C. until the isocyanate content had fallen below 0.1%. Cooling was then effected. The product was obtained as a light yellow liquid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US08222314B2 |
|---|
| 出典データセット | uspto-grants-2012_07 |
|---|
| ORD ID | ord-0e3ede740f0f406f8cd99529b1816b7b |
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| 出典メモ | uspto-grants-2012_07 |
|---|
