Benzene, 1-chloro-3-isocyanato- → 2-{[(3-Chlorophenyl)carbamoyl]oxy}ethyl prop-2-enoate

Participants

Role	Name	HCID	Charge
Reactant	Benzene, 1-chloro-3-isocyanato-	HCID 17968	—
Reactant	2,6-Di-tert-butyl-4-methylphenol	HCID 31404	—
Reactant	N,N',N''-Tris(3-dimethylaminopropyl)hexahydro-S-triazine	HCID 85160	—
Reactant	Isocyanate	HCID 105034	—
Reactant	3-Hydroxybutyl acrylate	HCID 13932179	—
Product	2-{[(3-Chlorophenyl)carbamoyl]oxy}ethyl prop-2-enoate	HCID 68551065	—

Reaction Conditions

Temperature	60 °C

Reaction Steps

0.15 g of 2,6-di-tert-butyl-4-methylphenol, 0.075 g of Desmorapid Z, 85.3 g of 3-chlorophenyl isocyanate were initially introduced into a 500 ml round-bottomed flask and heated to 60° C. Thereafter, 65.5 g of 3-hydroxybutyl acrylate were added dropwise and the mixture was kept further at 60° C. until the isocyanate content had fallen below 0.1%. Cooling was then effected. The product was obtained as a crystalline solid.

Provenance & Evidence

DOI	10.6084/m9.figshare.5104873.v1
Patent number	US08222314B2
Source dataset	uspto-grants-2012_07
ORD ID	ord-64d0e7a4b40344aab7673c126f012775
Source note	uspto-grants-2012_07