HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1514835Generated: November 3, 2026
2,6-Di-tert-butyl-4-methylphenol → 2-{[(3-Bromophenyl)carbamoyl]oxy}ethyl prop-2-enoate
https://huagongshe.com/reaction/1514835
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 2,6-Di-tert-butyl-4-methylphenol | HCID 31404 | — |
| Reactant | N,N',N''-Tris(3-dimethylaminopropyl)hexahydro-S-triazine | HCID 85160 | — |
| Reactant | Isocyanate | HCID 105034 | — |
| Reactant | 3-Bromophenyl isocyanate | HCID 141001 | — |
| Reactant | 3-Hydroxybutyl acrylate | HCID 13932179 | — |
| Product | 2-{[(3-Bromophenyl)carbamoyl]oxy}ethyl prop-2-enoate | HCID 58833466 | — |
Reaction Steps
0.015 g of 2,6-di-tert.-butyl4-methylphenol, 0.007 g of Desmorapid Z, 9.4 g of 3-bromophenyl isocyanate were initially introduced in a 20 ml sample bottle and heated to 60° C. Thereafter, 5.5 g of 3-hydroxybutyl acrylate were added dropwise and the mixture was kept further at 60° C. until the isocyanate content had fallen below 0.1%. Cooling was then effected. The product was obtained as a crystalline solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US08222314B2 |
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| Source dataset | uspto-grants-2012_07 |
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| ORD ID | ord-9b129b99e8f243019b15630baa5b6f08 |
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| Source note | uspto-grants-2012_07 |
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