化工社化工社 化学情報印刷レポート · 研究参考用
Iodine → 1-Ethylsulfanylsulfonyl-4-methylbenzene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Iodine | HCID 807 | — |
| 反応物 | Diethyl disulfide | HCID 8077 | — |
| 反応物 | Sodium p-toluenesulfinate | HCID 2723791 | — |
| 生成物 | 1-Ethylsulfanylsulfonyl-4-methylbenzene | HCID 480041 | 100% |
反応手順
The reaction was carried out using 0.60 mL (4.87 mmoL) of diethyl disulfide, 2.78 g (15.6 mmoL) of sodium p-toluenesulfinate, 2.47 g (9.74 mmoL) of iodine in accordance with the method of Reference Example 3, and the obtained residue was purified by silica gel column chromatography (hexane:ethyl acetate=8:1) to obtain 2.11 g of the heading compound as a colorless oily substance (yield 100%).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08222407B2 |
| 出典データセット | uspto-grants-2012_07 |
| ORD ID | ord-e4712a18d0d144cbaaf6ae12dbb30cd8 |
| 出典メモ | uspto-grants-2012_07 |