Dimethylanilinium chloride → N,N-dimethylphenylammonium tetrakis(tritert-butylsilylethynyl)borate

HRID 1515392Notes

Reaction equation

HRID 1515392 reaction equation
[C:1]([Si:5]([C:14]#[C:15][B-:16]([C:47]#[C:48][Si:49]([C:58]([CH3:61])([CH3:60])[CH3:59])([C:54]([CH3:57])([CH3:56])[CH3:55])[C:50]([CH3:53])([CH3:52])[CH3:51])([C:32]#[C:33][Si:34]([C:43]([CH3:46])([CH3:45])[CH3:44])([C:39]([CH3:42])([CH3:41])[CH3:40])[C:35]([CH3:38])([CH3:37])[CH3:36])[C:17]#[C:18][Si:19]([C:28]([CH3:31])([CH3:30])[CH3:29])([C:24]([CH3:27])([CH3:26])[CH3:25])[C:20]([CH3:23])([CH3:22])[CH3:21])([C:10]([CH3:13])([CH3:12])[CH3:11])[C:6]([CH3:9])([CH3:8])[CH3:7])([CH3:4])([CH3:3])[CH3:2].[Li+].[Cl-].[CH3:64][NH+:65]([C:67]1[CH:72]=[CH:71][CH:70]=[CH:69][CH:68]=1)[CH3:66]>C1(C)C=CC=CC=1>[C:54]([Si:49]([C:48]#[C:47][B-:16]([C:15]#[C:14][Si:5]([C:1]([CH3:4])([CH3:3])[CH3:2])([C:6]([CH3:9])([CH3:8])[CH3:7])[C:10]([CH3:13])([CH3:12])[CH3:11])([C:17]#[C:18][Si:19]([C:20]([CH3:23])([CH3:22])[CH3:21])([C:24]([CH3:27])([CH3:26])[CH3:25])[C:28]([CH3:31])([CH3:30])[CH3:29])[C:32]#[C:33][Si:34]([C:43]([CH3:46])([CH3:45])[CH3:44])([C:39]([CH3:41])([CH3:40])[CH3:42])[C:35]([CH3:36])([CH3:37])[CH3:38])([C:50]([CH3:53])([CH3:52])[CH3:51])[C:58]([CH3:61])([CH3:60])[CH3:59])([CH3:55])([CH3:56])[CH3:57].[CH3:64][NH+:65]([C:67]1[CH:72]=[CH:71][CH:70]=[CH:69][CH:68]=1)[CH3:66]

Participants

4

Reactant 2

HCID 11789467Dimethylanilinium chlorideHCID 86638769Lithium tetrakis(tritert-butylsilylethynyl)borate

Product 1

HCID 86638767N,N-dimethylphenylammonium tetrakis(tritert-butylsilylethynyl)borate

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

Lithium tetrakis(tritert-butylsilylethynyl)borate is dissolved in toluene and one equivalent of N,N-dimethylphenylammonium chloride is added. The LiCl which has precipitated out is filtered off. After removal of the toluene in vacuo, N,N-dimethylphenylammonium tetrakis(tritert-butylsilylethynyl)borate is obtained.

Workup

  1. customThe LiCl which has precipitated out
  2. filtrationis filtered off
  3. customAfter removal of the toluene in vacuo

Sources & evidence

ORD record
ord-1ff01850234c441ea244c55563e8f7be
Source dataset
uspto-grants-2012_07
Patent number
US08222457B2

Reaction notes

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