Dimethylanilinium chloride → N,N-dimethylphenylammonium tetrakis(triisopropylsilylethynyl)borate

HRID 1515393Notes

Reaction equation

HRID 1515393 reaction equation
[CH:1]([Si:4]([C:11]#[C:12][B-:13]([C:38]#[C:39][Si:40]([CH:47]([CH3:49])[CH3:48])([CH:44]([CH3:46])[CH3:45])[CH:41]([CH3:43])[CH3:42])([C:26]#[C:27][Si:28]([CH:35]([CH3:37])[CH3:36])([CH:32]([CH3:34])[CH3:33])[CH:29]([CH3:31])[CH3:30])[C:14]#[C:15][Si:16]([CH:23]([CH3:25])[CH3:24])([CH:20]([CH3:22])[CH3:21])[CH:17]([CH3:19])[CH3:18])([CH:8]([CH3:10])[CH3:9])[CH:5]([CH3:7])[CH3:6])([CH3:3])[CH3:2].[Li+].[Cl-].[CH3:52][NH+:53]([C:55]1[CH:60]=[CH:59][CH:58]=[CH:57][CH:56]=1)[CH3:54]>C1(C)C=CC=CC=1>[CH:44]([Si:40]([C:39]#[C:38][B-:13]([C:14]#[C:15][Si:16]([CH:17]([CH3:19])[CH3:18])([CH:20]([CH3:22])[CH3:21])[CH:23]([CH3:25])[CH3:24])([C:12]#[C:11][Si:4]([CH:1]([CH3:3])[CH3:2])([CH:5]([CH3:7])[CH3:6])[CH:8]([CH3:10])[CH3:9])[C:26]#[C:27][Si:28]([CH:35]([CH3:36])[CH3:37])([CH:32]([CH3:33])[CH3:34])[CH:29]([CH3:30])[CH3:31])([CH:41]([CH3:43])[CH3:42])[CH:47]([CH3:48])[CH3:49])([CH3:45])[CH3:46].[CH3:52][NH+:53]([C:55]1[CH:60]=[CH:59][CH:58]=[CH:57][CH:56]=1)[CH3:54]

Participants

4

Reactant 2

HCID 11789467Dimethylanilinium chlorideHCID 86638772Lithium tetrakis(triisopropylsilylethynyl)borate

Product 1

HCID 86638770N,N-dimethylphenylammonium tetrakis(triisopropylsilylethynyl)borate

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

Lithium tetrakis(triisopropylsilylethynyl)borate is dissolved in toluene and one equivalent of N,N-dimethylphenylammonium chloride is added. The LiCl which has precipitated out is filtered off. After removal of the toluene in vacuo, N,N-dimethylphenylammonium tetrakis(triisopropylsilylethynyl)borate is obtained.

Workup

  1. customThe LiCl which has precipitated out
  2. filtrationis filtered off
  3. customAfter removal of the toluene in vacuo

Sources & evidence

ORD record
ord-1cc68b89aeb94cb3b59e7cfd30d13016
Source dataset
uspto-grants-2012_07
Patent number
US08222457B2

Reaction notes

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