HRID1515393

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID11789467

未命名化合物

结构：CC(C)[Si](C#C[B-](C#C[Si](C(C)C)(C(C)C)C(C)C)(C#C[Si](C(C)C)(C(C)C)C(C)C)C#C[Si](C(C)C)(C(C)C)C(C)C)(C(C)C)C(C)C.[Li+]

HCID86638772

未命名化合物

PRODUCTS

生成物

结构：CC(C)[Si](C#C[B-](C#C[Si](C(C)C)(C(C)C)C(C)C)(C#C[Si](C(C)C)(C(C)C)C(C)C)C#C[Si](C(C)C)(C(C)C)C(C)C)(C(C)C)C(C)C.C[NH+](C)c1ccccc1

HCID86638770

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID1140

Toluene

C7H8

PROCEDURE

实验过程

Lithium tetrakis(triisopropylsilylethynyl)borate is dissolved in toluene and one equivalent of N,N-dimethylphenylammonium chloride is added. The LiCl which has precipitated out is filtered off. After removal of the toluene in vacuo, N,N-dimethylphenylammonium tetrakis(triisopropylsilylethynyl)borate is obtained.

WORKUP

后处理

customThe LiCl which has precipitated out
filtrationis filtered off
customAfter removal of the toluene in vacuo

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-1cc68b89aeb94cb3b59e7cfd30d13016
来源数据集: uspto-grants-2012_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08222457B2
来源说明: uspto-grants-2012_07

反应 SMILES

[CH:1]([Si:4]([C:11]#[C:12][B-:13]([C:38]#[C:39][Si:40]([CH:47]([CH3:49])[CH3:48])([CH:44]([CH3:46])[CH3:45])[CH:41]([CH3:43])[CH3:42])([C:26]#[C:27][Si:28]([CH:35]([CH3:37])[CH3:36])([CH:32]([CH3:34])[CH3:33])[CH:29]([CH3:31])[CH3:30])[C:14]#[C:15][Si:16]([CH:23]([CH3:25])[CH3:24])([CH:20]([CH3:22])[CH3:21])[CH:17]([CH3:19])[CH3:18])([CH:8]([CH3:10])[CH3:9])[CH:5]([CH3:7])[CH3:6])([CH3:3])[CH3:2].[Li+].[Cl-].[CH3:52][NH+:53]([C:55]1[CH:60]=[CH:59][CH:58]=[CH:57][CH:56]=1)[CH3:54]>C1(C)C=CC=CC=1>[CH:44]([Si:40]([C:39]#[C:38][B-:13]([C:14]#[C:15][Si:16]([CH:17]([CH3:19])[CH3:18])([CH:20]([CH3:22])[CH3:21])[CH:23]([CH3:25])[CH3:24])([C:12]#[C:11][Si:4]([CH:1]([CH3:3])[CH3:2])([CH:5]([CH3:7])[CH3:6])[CH:8]([CH3:10])[CH3:9])[C:26]#[C:27][Si:28]([CH:35]([CH3:36])[CH3:37])([CH:32]([CH3:33])[CH3:34])[CH:29]([CH3:30])[CH3:31])([CH:41]([CH3:43])[CH3:42])[CH:47]([CH3:48])[CH3:49])([CH3:45])[CH3:46].[CH3:52][NH+:53]([C:55]1[CH:60]=[CH:59][CH:58]=[CH:57][CH:56]=1)[CH3:54]