2-Chloro-3-nitrothiophene → HCID 68756959, compound

HRID 1519901Notes

Reaction equation

HRID 1519901 reaction equation
C([Sn](CCCC)(CCCC)[C:6]1[N:7]=[CH:8][S:9][CH:10]=1)CCC.Cl[C:20]1[S:21][CH:22]=[CH:23][C:24]=1[N+:25]([O-:27])=[O:26]>>[N+:25]([C:24]1[CH:23]=[CH:22][S:21][C:20]=1[C:6]1[N:7]=[CH:8][S:9][CH:10]=1)([O-:27])=[O:26]

Participants

3

Reactant 2

HCID 2201862-Chloro-3-nitrothiopheneHCID 27632584-(Tri-n-butylstannyl)thiazole

Product 1

HCID 68756959HCID 68756959, compound

Procedure

4-(3-Nitrothiophen-2-yl)thiazole was prepared from 4-(tributylstannyl)thiazole (0.51 g, 1.31 mmol) and 2-chloro-3-nitrothiophene (0.21 g, 1.31 mmol) according to protocol E. Retention time (min)=2.012, method [1], MS(ESI) 212.9 (M+H).

Sources & evidence

ORD record
ord-7baacfdb3bdd48e9bcba77aa1fe1b591
Source dataset
uspto-grants-2015_07
Patent number
US09073891B2

Reaction notes

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