HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-Thiocresol → 1-Bromo-2-(2-chloro-4-methoxy-phenylsulfanyl)-5-fluoro-benzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-Thiocresol | HCID 7930 | — |
| Reactant | m-Toluidine | HCID 7934 | — |
| Reactant | 2-Bromo-4-fluoroaniline | HCID 242873 | — |
| Reactant | 2-Chloro-1-iodo-4-methoxybenzene | HCID 18001519 | — |
| Reactant | 2-Bromo-4-fluorobenzene-1-thiol | HCID 26597085 | — |
| Product | 1-Bromo-2-(2-chloro-4-methoxy-phenylsulfanyl)-5-fluoro-benzene | HCID 68684845 | — |
Reaction Steps
Prepared from 2-chloro-1-iodo-4-methoxy-benzene and 2-bromo-4-fluoro-benzenethiol (prepared from 2-bromo-4-fluoro-phenylamine by diazotization according to the procedure reported for the conversion of 3-toluidine to 3-thiocresol by Tarbell and Fukushima J. Am. Chem. Soc. 1946, 68, 1456-1460).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07732463B2 |
| Source dataset | uspto-grants-2010_06 |
| ORD ID | ord-673b76bb73c640d5863b0162dca50204 |
| Source note | uspto-grants-2010_06 |