참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Octanoic Acid | HCID 379 | — |
| 반응물 | 2-Ethyl-1-butanol | HCID 7358 | — |
| 촉매 | Oxalate;tin(4+) | HCID 9839089 | — |
| 용매 | Water | HCID 962 | — |
| 생성물 | 2-Ethylbutyl octanoate | HCID 229894 | 76% |
반응 단계
187.2 g (1.3 mol) of caprylic acid, 214.0 g (2.09 mol) of 2-ethylbutanol and 0.14 g of tin oxalate (“Fascat 2001”) were heated to 160° C. under N2, during which water separation was observed. Once water separation had subsided, the mixture was heated to 210° C. in 10° C. steps. This temperature was then held for 3 h. Then, firstly the excess alcohol was removed by distillation and then the product was distilled at 8-12 mbar and 136-141° C. The product (225.6 g) was obtained as a clear liquid with an acid number of 0.47 and an OH number of 1.36.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US09079850B2 |
|---|
| 출처 데이터셋 | uspto-grants-2015_07 |
|---|
| ORD ID | ord-c34136ba501744b982ddf3faad09fbd8 |
|---|
| 출처 메모 | uspto-grants-2015_07 |
|---|
