1-Butyl-5-chloroindoline-2,3-dione → 1-Butyl-5-chloro-2-oxoindolin-3-yl benzoate

HRID 1523032Notes

Reaction equation

HRID 1523032 reaction equation
[C:1](OC1C2C(=CC=C(C)C=2)N(CC)C1=O)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH2:23]([N:27]1[C:35]2[C:30](=[CH:31][C:32]([Cl:36])=[CH:33][CH:34]=2)[C:29](=[O:37])[C:28]1=[O:38])[CH2:24][CH2:25][CH3:26]>>[C:1]([O:37][CH:29]1[C:30]2[C:35](=[CH:34][CH:33]=[C:32]([Cl:36])[CH:31]=2)[N:27]([CH2:23][CH2:24][CH2:25][CH3:26])[C:28]1=[O:38])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 47368621-Butyl-5-chloroindoline-2,3-dioneHCID 904159121-Ethyl-5-methyl-2-oxoindolin-3-yl benzoate

Product 1

HCID 904169811-Butyl-5-chloro-2-oxoindolin-3-yl benzoate

Procedure

Was made in an analogous fashion to 1-ethyl-5-methyl-2-oxoindolin-3-yl benzoate using 1-butyl-5-chloroindoline-2,3-dione. 1H NMR δ 8.11 (t, 2H), 7.60 (t, 1H), 7.44 (m, 3H), 7.33 (d, 1H), 6.82 (d, 1H), 6.10 (s, 1H), 3.73 (m, 2H), 1.72 (m, 2H), 1.44 (m, 2H), 0.99 (t, 3H).

Sources & evidence

ORD record
ord-a57e775c7ff64026a817e22b2a24a173
Source dataset
uspto-grants-2015_07
Patent number
US09079853B2

Reaction notes

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