1-(3-methylbutyl)-1H-indole-2,3-dione → 1-Isopentyl-2-oxoindolin-3-yl benzoate

HRID 1523034Notes

Reaction equation

HRID 1523034 reaction equation
[C:1]([O:9][CH:10]1[C:18]2[C:13](=[CH:14][CH:15]=[C:16](C)[CH:17]=2)[N:12]([CH2:20][CH3:21])[C:11]1=[O:22])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH2:23](N1C2C(=CC=CC=2)C(=O)C1=O)[CH2:24][CH:25](C)C>>[C:1]([O:9][CH:10]1[C:18]2[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=2)[N:12]([CH2:20][CH2:21][CH:24]([CH3:25])[CH3:23])[C:11]1=[O:22])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 23625931-(3-methylbutyl)-1H-indole-2,3-dioneHCID 904159121-Ethyl-5-methyl-2-oxoindolin-3-yl benzoate

Product 1

HCID 904174431-Isopentyl-2-oxoindolin-3-yl benzoate

Procedure

Was made in an analogous fashion to 1-ethyl-5-methyl-2-oxoindolin-3-yl benzoate using 1-isopentylindoline-2,3-dione. 1H-NMR δ 8.10 (d, 2H), 7.59 (t, 1H), 7.46 (dd, 2H), 7.61-7.34 (m, 2H), 7.06 (t, 1H), 6.88 (d, 1H), 6.18 (s, 1H), 3.78 (m, 2H), 1.77-1.60 (m, 3H), 1.02 (dd, 6H).

Sources & evidence

ORD record
ord-3e8d0f06dfd343b4ac8d92639aba8477
Source dataset
uspto-grants-2015_07
Patent number
US09079853B2

Reaction notes

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