5-Chloro-1-isopentylindoline-2,3-dione → 5-Chloro-1-isopentyl-2-oxoindolin-3-yl benzoate

HRID 1523042Notes

Reaction equation

HRID 1523042 reaction equation
[C:1](OC1C2C(=CC=CC=2)N(CCC)C1=O)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Cl:23][C:24]1[CH:25]=[C:26]2[C:30](=[CH:31][CH:32]=1)[N:29]([CH2:33][CH2:34][CH:35]([CH3:37])[CH3:36])[C:28](=[O:38])[C:27]2=[O:39]>>[C:1]([O:39][CH:27]1[C:26]2[C:30](=[CH:31][CH:32]=[C:24]([Cl:23])[CH:25]=2)[N:29]([CH2:33][CH2:34][CH:35]([CH3:36])[CH3:37])[C:28]1=[O:38])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 2

HCID 47368645-Chloro-1-isopentylindoline-2,3-dioneHCID 904164392-Oxo-1-propylindolin-3-yl benzoate

Product 1

HCID 904180205-Chloro-1-isopentyl-2-oxoindolin-3-yl benzoate

Procedure

This compound was prepared in a similar way to 2-oxo-1-propylindolin-3-yl benzoate starting from 5-chloro-1-isopentylindoline-2,3-dione. 1H-NMR δ 8.11 (dd, 2H), 7.60 (dt, 1H), 7.47 (m, 2H) 7.45 (m, 3H), 7.33 (dd, 1H), 6.80 (d, 1H), 6.10 (d, 1H), 3.76 (m, 2H), 1.72 (m, 1H), 1.01 (dd, 6H).

Sources & evidence

ORD record
ord-0737eb9ec4344af8aa67e8da509af5ae
Source dataset
uspto-grants-2015_07
Patent number
US09079853B2

Reaction notes

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