HuagongsheHuagongshe Chemistry Print Report · For research reference only
3,4-Dimethoxybenzyl bromide → 3-(3,4-Dimethoxybenzyl)-1-isopentyl-5-methyl-2-oxoindolin-3-yl benzoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3,4-Dimethoxybenzyl bromide | HCID 10900458 | — |
| Reactant | 1-Ethyl-5-methyl-2-oxo-3-(3,4,5-trimethoxybenzyl)indolin-3-yl benzoate | HCID 86300681 | — |
| Reactant | 1-Isopentyl-5-methyl-2-oxoindolin-3-yl benzoate | HCID 90414979 | — |
| Product | 3-(3,4-Dimethoxybenzyl)-1-isopentyl-5-methyl-2-oxoindolin-3-yl benzoate | HCID 90418326 | — |
Reaction Steps
This compound was made in an analogous fashion to 1-ethyl-5-methyl-2-oxo-3-(3,4,5-trimethoxybenzyl)indolin-3-yl benzoate using 1-isopentyl-5-methyl-2-oxoindolin-3-yl benzoate and 4-(bromomethyl)-1,2-dimethoxybenzene. 1H-NMR δ 8.06 (d, 2H), 7.57 (t, 1H), 7.43 (t, 2H), 7.08 (d, 1H), 6.93 (s, 1H), 6.67 (d, 1H), 6.60 (t, 2H), 6.36 (s, 1H), 3.82 (s, 3H), 3.64 (m, 4H), 3.46 (m, 2H), 3.26 (d, 1H), 2.27 (s, 3H), 1.50 (m, 1H), 1.26 (m, 2H) 0.92 (dd, 6H).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09079853B2 |
| Source dataset | uspto-grants-2015_07 |
| ORD ID | ord-5109fafe4d124acfb484256ed4adc51d |
| Source note | uspto-grants-2015_07 |