Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzyl propionate → Indolizine-1,3-dicarboxylic acid 3-allyl ester 1-benzyl ester
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzyl propionate | HCID 31219 | — |
| 반응물 | Prop-2-enyl 2-bromoacetate | HCID 527610 | — |
| 반응물 | 1-Isocyanato-indolizine-3-carboxylic acid benzyl ester | HCID 86673812 | — |
| 생성물 | Indolizine-1,3-dicarboxylic acid 3-allyl ester 1-benzyl ester | HCID 68283672 | — |
반응 단계
The title compound was prepared using the protocol described in steps A and B for the preparation of 1-isocyanato-indolizine-3-carboxylic acid benzyl ester scheme A6 using bromo-acetic acid allyl ester in step A and propionic acid benzyl ester in step B. TLC, Rf (c-hexane/EtOAc 1:1)=0.8; MS (LC/MS): 336.1 [M+H]+, 358.1 [M+Na]+, 693.2 [2M+Na]+; tR (HPLC conditions a): 4.55 min.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US09085555B2 |
| 출처 데이터셋 | uspto-grants-2015_07 |
| ORD ID | ord-9c9717122e8748bbace1fdd3a9ed42ae |
| 출처 메모 | uspto-grants-2015_07 |