HCID 46180174, compound → HCID 25235419, compound

HRID 1527663Notes

Reaction equation

HRID 1527663 reaction equation
[CH3:1][C:2]1[C:7](/[CH:8]=[C:9](\[CH3:13])/[C:10]([OH:12])=[O:11])=[C:6]([O:14]C)[C:5]([O:16][CH3:17])=[C:4]([O:18][CH3:19])[C:3]=1[O:20]C>CCOCC>[CH3:19][O:18][C:4]1[C:3](=[O:20])[C:2]([CH3:1])=[C:7](/[CH:8]=[C:9](\[CH3:13])/[C:10]([OH:12])=[O:11])[C:6](=[O:14])[C:5]=1[O:16][CH3:17]

Participants

3

Reactant 1

HCID 46180174HCID 46180174, compound

Product 1

HCID 25235419HCID 25235419, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

Compound 10b was prepared from 9b (0.057 g, 0.19 mmol) as described above for 10a using Method B to give 0.016 g (0.060 mmol, 31%) of the product as a red solid following flash chromatography (1:1 Et2O:hexanes 0.5% AcOH) and recrystallization from Et2O/hexanes.

Workup

  1. customto give

Sources & evidence

ORD record
ord-0c04f0542a9e46a7a6c168a8c676ff75
Source dataset
uspto-grants-2015_07
Patent number
US09089605B2

Reaction notes

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