HCID 46180237, compound → HCID 46179964, compound

HRID 1527664Notes

Reaction equation

HRID 1527664 reaction equation
[CH3:1][C:2]1[C:7](/[CH:8]=[C:9](\[CH2:13][CH3:14])/[C:10]([OH:12])=[O:11])=[C:6]([O:15]C)[C:5]([O:17][CH3:18])=[C:4]([O:19][CH3:20])[C:3]=1[O:21]C>CCOCC>[CH3:20][O:19][C:4]1[C:3](=[O:21])[C:2]([CH3:1])=[C:7](/[CH:8]=[C:9](\[CH2:13][CH3:14])/[C:10]([OH:12])=[O:11])[C:6](=[O:15])[C:5]=1[O:17][CH3:18]

Participants

3

Reactant 1

HCID 46180237HCID 46180237, compound

Product 1

HCID 46179964HCID 46179964, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

Compound 10c was prepared from 9c (0.010 g, 0.033 mmol) as described above for 10a to give 0.003 g (0.010 mmol, 32%) of the product as a red solid following flash chromatography (1:1 Et2O:hexanes 0.5% AcOH) and recrystallization from Et2O/hexanes.

Workup

  1. customto give

Sources & evidence

ORD record
ord-f973dbf1758f41de931c6e67dea6e30c
Source dataset
uspto-grants-2015_07
Patent number
US09089605B2

Reaction notes

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