HCID 46180239, compound → HCID 46179965, compound

HRID 1527665Notes

Reaction equation

HRID 1527665 reaction equation
[CH3:1][C:2]1[C:7](/[CH:8]=[C:9](\[CH2:13][CH2:14][CH3:15])/[C:10]([OH:12])=[O:11])=[C:6]([O:16]C)[C:5]([O:18][CH3:19])=[C:4]([O:20][CH3:21])[C:3]=1[O:22]C>CCOCC>[CH3:21][O:20][C:4]1[C:3](=[O:22])[C:2]([CH3:1])=[C:7](/[CH:8]=[C:9](\[CH2:13][CH2:14][CH3:15])/[C:10]([OH:12])=[O:11])[C:6](=[O:16])[C:5]=1[O:18][CH3:19]

Participants

3

Reactant 1

HCID 46180239HCID 46180239, compound

Product 1

HCID 46179965HCID 46179965, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

Compound 10d was prepared from 9d (0.029 g, 0.090 mmol) as described above for 10a to give 0.016 g (0.053 mmol, 59%) of the product as a red solid following flash chromatography (1:1 Et2O:hexanes 0.5% AcOH) and recrystallization from Et2O/hexanes.

Workup

  1. customto give

Sources & evidence

ORD record
ord-9bc01b339ef747e696dcb1b75f0786de
Source dataset
uspto-grants-2015_07
Patent number
US09089605B2

Reaction notes

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