HCID 46180040, compound → HCID 25235422, compound

HRID 1527668Notes

Reaction equation

HRID 1527668 reaction equation
[CH3:1][C:2]1[C:7](/[CH:8]=[C:9](\[CH2:13][CH2:14][O:15][CH3:16])/[C:10]([OH:12])=[O:11])=[C:6]([O:17]C)[C:5]([O:19][CH3:20])=[C:4]([O:21][CH3:22])[C:3]=1[O:23]C>CCOCC>[CH3:22][O:21][C:4]1[C:3](=[O:23])[C:2]([CH3:1])=[C:7](/[CH:8]=[C:9](\[CH2:13][CH2:14][O:15][CH3:16])/[C:10]([OH:12])=[O:11])[C:6](=[O:17])[C:5]=1[O:19][CH3:20]

Participants

3

Reactant 1

HCID 46180040HCID 46180040, compound

Product 1

HCID 25235422HCID 25235422, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

Compound 64 was prepared from 96 (0.070 g, 0.21 mmol) as described above for 10a using Method A to give 0.012 g (0.039 mmol, 19%) of the product as a red solid following flash chromatography (2:3 Et2O:hexanes 0.5% AcOH) and recrystallization from Et2O/hexanes.

Workup

  1. customto give

Sources & evidence

ORD record
ord-1e2aa10be9cf4b858f46528013d0df88
Source dataset
uspto-grants-2015_07
Patent number
US09089605B2

Reaction notes

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