HCID 178476752, compound → HCID 178476751, compound
Reaction equation
[Zn:1]([O:6][C:7]([CH3:9])=[O:8])[O:2][C:3]([CH3:5])=[O:4].O.O>CO>[Zn:1]([O:6][C:7]([CH3:9])=[O:8])[O:2][C:3]([CH3:5])=[O:4]Participants
3
Reactant 1
Product 1
Reagents, catalysts & solvents 1
Procedure
111.45 g of MeOH was added to Zn(OAc)2.2H2O in a 3-necked RBF to form 0.595 mol·L−1 Zn(OAc)2 methanolic solution (1.134 L). 18.43 g of KOH was dissolved in MeOH to form 1.134 L KOH solution with a concentration of 1.01 mol·L−1. The KOH solution was mixed with the Zn(OAc)2 methanolic solution under vigorous stirring in RPF. The reaction temperature of the system was maintained at 62° C. seconds after the KOH solution was mixed with the Zn(OAc)2 methanolic solution, 0.05 mol·L−1 sodium oleate aqueous solution (0.448 L) was added to the reaction solution. White precipitate formed almost immediately after the addition of sodium oleate. The reaction solution was aged at 62° C. for 10 minutes.
Sources & evidence
- ORD record
- ord-6c4141cb2d2a457d944da11ecac9a0e3
- Source dataset
- uspto-grants-2015_07
- Patent number
- US09090468B2
Reaction notes
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